
The chemical composition of the Capsicum species includes a fixed oil, pungent principles, volatile oil, and carotenoid, mostly capsanthin, pigments. An oleoresin is obtained by solvent extraction. Capsicum frutescens L. is much more pungent than Capsicum annuum L.
Capsaicin is 8-methyl-N-(2-hydroxy-3-methoxyphenyl)non-6-enamide. In its pure form, it is a red crystalline solid at room temperature. Structurally, it is related to the chemical vanillin, which gives vanilla its scent and flavour. The big fatty side chain sticking off the vanillin ring makes capsaicin quite insoluble in water, which is one of the reasons why drinking water to quench the burn is a waste of time. If you really want to stop the burn (and why would you want to do that?), the best bet is to drink milk, lassi or neat vodka: capsaicin is soluble in most fats and alcohol.
As a medicinal plant, the Capsicum species has been used as a carminative, digestive irritant, stomachic, stimulant, rubefacient, and tonic. The plants have also been used as folk remedies for dropsy, colic, diarrhea, asthma, arthritis, muscle cramps, and toothache.

Other Capsicum species of some importance include Capsicum chinense, Capsicum pendulum, Capsicum pubescens, and Capsicum minimum. Black and white pepper come from Piper nigrens L., of the Piperaceae family.
Capsicum annuum L. and Capsicum frutescens L. are generally recognized as safe for human consumption as spices/natural flavorings and as plant extracts or oleoresins.
http://en.wikipedia.org/wiki/Capsicum
http://www.calantilles.com/capsicum_peppers.html
http://www.botany.com/capsicum.htm
http://www.calantilles.com/capsicum_peppers.html
http://www.botany.com/capsicum.htm
Courtesy: Various Sources over internet
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